Fabrication of Nanodots Using Microphase Separation of Block Copolymer

نویسندگان

  • A. Bradshaw
  • T. Tanaka
  • N. Takeyasu
  • A. Taguchi
  • S. Kawata
  • Andrew Bradshaw
  • Takuo Tanaka
  • Nobuyuki Takeyasu
  • Atsushi Taguchi
  • Satoshi Kawata
چکیده

Silicon microchips have continued to grow progressively smallerto meet the demands of a competitive market. The next step indevelopment will send the chips from micro-order to nano-order,giving rise to new and challenging complications. Here, twomethods are explored to develop such technology. The firstinvolves molecular beam epitaxial (MBE) growth of isotopicallycontrolled Si-based quantum computers. Manual scoring ofisotopically pure 28-Si chip followed by kink-up DC correcting andsubsequent 29-Si addition leaves equally distributed lines of 29-Siwith controllable nuclear spin. Capping the lines on one end withNi/Fe magnets and on the other end with P atoms, individual spincan be read out and controlled using NMR. The second methodinvolves modifying the traditional Metal Oxide SemiconductorField Effect Transistor (MOS FET) for successful nano-scaleoperation. Excessive boron diffusion causes unwanted digitallogic stage switching in nano-order MOS FET, so methods tocontrol boron diffusion, transient and oxygen enhanced diffusion,are studied.Building The All-Silicon Model The All-Silicon ModelBackgroundGordon Moore’s Law: Market transistors need toprogressively decrease in size by a factor of two everytwo years -Quantum Challenge: Progressing from micro tonanoscale transistors presents new physical andmethodological hurdles -Adaptation versus Innovation: Creating new transistordesigns or reinventing old ones 29Si atoms are positioned regularly in chains in a 7-Teslamagnetic field A 2-Tesla Ni/Fe magnet at one end of the chainindividualizes the spin of each 29SI atom Nuclear Magnetic Resonance (NMR) is used to locate each29Si atom and control its spin direction A phosphorus atom at the opposite end of the chainallows NMR to differentiate between multiple chains In the coming years, it is projected that exact positioningof 29Si and precise NMR readout will allow development ofthe first working All-Silicon Quantum Computer1. Manual scoring of 28Si chips produces regular step arrays2. Subsequent DC heating corrects nanoscale imperfections3. Controlled exposure to natural Silicon allows chains of 29Sito form on the apex of each step

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Lifshitz points in blends of AB and BC diblock copolymers

– We consider microand macro-phase separation in blends of AB and BC flexible diblock copolymers. We show that, depending on architecture, a number of phase diagram topologies are possible. Microphase separation or macrophase separation can occur, and there are a variety of possible Lifshitz points. Because of the rich parameter space, Lifshitz points of multiple order are possible. We demonstr...

متن کامل

Reaction-Induced Microphase Separation in Epoxy Thermosets Containing Block Copolymers Composed of Polystyrene and Poly(-caprolactone): Influence of Copolymer Architectures on Formation of Nanophases

We report an investigation of the influence of block copolymer architectures on formation of nanophases in epoxy thermosets via reactioninduced microphase separation approach. Toward this end, three binary block copolymers composed of polystyrene (PS) and poly(ε-caprolactone) (PCL) were synthesized via the combination of ring-opening polymerization (ROP) and atomic transfer radical polymerizati...

متن کامل

Photoinduced microphase separation in block copolymers: exploring shape incompatibility of mesogenic side groups.

Photoinduced microphase separation in block copolymers (BCP) was achieved for the first time, using a rationally designed diblock copolymer composed of two side-chain liquid crystalline polymers (SCLCP). The miscibility of the two blocks was promoted by the miscibility between the two types of mesognic side groups, while upon UV exposure inducing the trans-cis isomerization of azobenzene mesoge...

متن کامل

Microphase separation induced in the melt of Pluronic copolymers by blending with a hydrogen bonding urea-urethane end-capped supramolecular polymer.

Blending with a hydrogen-bonding supramolecular polymer is shown to be a successful novel strategy to induce microphase-separation in the melt of a Pluronic polyether block copolymer. The supramolecular polymer is a polybutadiene derivative with urea-urethane end caps. Microphase separation is analysed using small-angle X-ray scattering and its influence on the macroscopic rheological propertie...

متن کامل

Melt-Formable Block Copolymer Electrolytes for Lithium Rechargeable Batteries

Microphase separated block copolymers consisting of an amorphous poly~ethylene oxide! ~PEO!-based polymer covalently bound to a second polymer offer a highly attractive avenue to achieving both dimensional stability and high ionic conductivity in polymer electrolytes for solid-state rechargeable lithium batteries. However, due to the strong thermodynamic incompatibility typically found for most...

متن کامل

Microphase separation in polyelectrolytic diblock copolymer melt: weak segregation limit.

The authors present a generalized theory of microphase separation for charged-neutral diblock copolymer melt. The stability limit of the disordered phase for salt-free melt has been calculated using random phase approximation (RPA) and self-consistent-field theory (SCFT). Explicit analytical free energy expressions for different classical ordered microstructures (lamellar, cylinder, and sphere)...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2007